过氧化二苯甲酰

过氧化二苯甲酰 (1)化学品及企业标识 化学品中文名 过氧化二苯甲酰;过氧化苯甲酰;过氧化二苯基乙二醛 化学品英文名 benzoyl peroxide; Benzoyl superoxide; Diphenylglyoxal peroxide 分子式 CHO 相对分子质量 242.24 14104 (2)成分/组成信息 ?纯品 混合物 有害物成分 浓度 CAS NO. 过氧化二苯甲酰 94-36-0 (3)危险性概述 危险性类别 第5.2类 有机过氧化物 侵入途径 吸入、食入 健康危害 本品对上呼吸道有刺激性。对皮肤有强烈刺激及致敏作用。进入眼内可造成损害。 环境危害 对环境可能有害。 燃爆危险 易燃。受撞击、摩擦，遇明火或其他点火源极易爆炸。 (4)急救措施 皮肤接触 立即脱去污染的衣着，用大量流动清水冲洗20,30min。如有不适感，就医。 眼睛接触 立即提起眼睑，用大量流动清水或生理盐水彻底冲洗10,15min。如有不适感，就医。 for more than 60 years of rural senior party member care funds; System of regulating the activities of grass-roots party organizations, and enhance the sense of belonging of grass-roots party members; Hold fast to implement "red credit", "red stake" two major project opportunities, strive to explore new ways of development of village collective economy, rural collective economy achieve breakthrough; A progress review by the Secretary of the party work of grass-roots party organizations, strengthens the responsibility of grasping party building, Party Secretary. Second, strengthening the construction of clean and honest Government and fight against corruption. Seriously implement the honest responsibility, actively carry out the independent Commission against corruption interview system, increase the leadership and the day-to-day supervision of party members and cadres at all levels, strengthen the not Winds of special treatment, treatment of "laid-back luxury and arrogance" and "three-pronged" problem, non-gang, national public officers, serving in leadership positions is not land, above-standard equipped with buses and cars for private purposes, and recreational city of gifts, hospitality, luxury and waste, "emptied the rating" special rectification work. Adhere to the rot will be punishing, corrupt Su, and 1 village, 4 disciplinary administrative cadres and workers. Three is to strengthen peace to create a work. Strengthen source management, adhere to prevention, focusing on prevention. Carry out the "big reception, big tour" campaign, petitioning for the cadres of the 吸入 迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。呼吸、心跳停止，立即进行心肺复苏术。就医。 食入 漱口，饮足量温水。就医。 (5)消防措施 危险特性 干燥状态下非常易燃，遇热、摩擦、振动或杂质污染均能引起爆炸性分解。急剧加热时可发生爆炸。与强酸、强碱、硫化物、还原剂、聚合用助催化剂和促进剂如二甲基苯胺、胺类或金属环烷酸盐接触会发生剧烈反应。 有害燃烧产物 一氧化碳 灭火方法 用水、雾状水、抗溶性泡沫、二氧化碳灭火 灭火注意事项及措施 消防人员须在有防爆掩蔽处操作。遇大火切勿轻易接近。在物料附件失火，需用水保持容器冷却。禁止用砂土压盖。 (6)泄露应急处理 应急行动 隔离泄露污染区，限制出入。消除所有点火源。建议应急处理人员戴防尘口罩，穿一般作业工作服，戴橡胶手套。勿使泄漏物与可燃物质(如木材、纸、油等)接触。用雾状水保持泄漏物湿润。尽可能切断泄漏源。小量泄露:用惰性、湿润的不燃吸收泄漏物，用洁净的非火花工具收集于一盖子较松的塑料容器中，待处理。大量泄露:用水湿润，并筑堤收容。防止泄漏物进入水体、下水道、地下室或限制性空间。在专家指导下清除。 (7)操作处置与储存 操作注意事项 密闭操作，局部排风。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴头罩型电动送风过滤式防尘呼吸器，穿for more than 60 years of rural senior party member care funds; System of regulating the activities of grass-roots party organizations, and enhance the sense of belonging of grass-roots party members; Hold fast to implement "red credit", "red stake" two major project opportunities, strive to explore new ways of development of village collective economy, rural collective economy achieve breakthrough; A progress review by the Secretary of the party work of grass-roots party organizations, strengthens the responsibility of grasping party building, Party Secretary. Second, strengthening the construction of clean and honest Government and fight against corruption. Seriously implement the honest responsibility, actively carry out the independent Commission against corruption interview system, increase the leadership and the day-to-day supervision of party members and cadres at all levels, strengthen the not Winds of special treatment, treatment of "laid-back luxury and arrogance" and "three-pronged" problem, non-gang, national public officers, serving in leadership positions is not land, above-standard equipped with buses and cars for private purposes, and recreational city of gifts, hospitality, luxury and waste, "emptied the rating" special rectification work. Adhere to the rot will be punishing, corrupt Su, and 1 village, 4 disciplinary administrative cadres and workers. Three is to strengthen peace to create a work. Strengthen source management, adhere to prevention, focusing on prevention. Carry out the "big reception, big tour" campaign, petitioning for the cadres of the 聚乙烯防毒服，戴橡胶手套。远离火种、热源。工作场所严禁吸烟。使用防爆型的通风系统和设备。避免产生粉尘。避免与还原剂、酸类、碱类、醇类接触。搬运时要轻装轻卸，防止包装及容器损坏。禁止震动、撞击和摩擦。配备相应品种和数量的消防器材及泄露应急处理设备。倒空的容器可能残留有害物。 储存注意事项 储存时以水作稳定剂，一般含水30%。库温应保持在2,25?。应与还原剂、酸类、碱类、醇类分开存放，切忌混储。不宜久存，以免变质。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有合适的材料收容泄漏物。禁止震动、撞击和摩擦。 (8)接触控制/个体防护 职业接触限值 中国 PC-TWA(mg/m):5 3 美国(ACGIH)TLV-TWA(mg/m):5 监测方法 无资料 工程控制 密闭操作，局部排风。提供安全淋浴和洗眼设备 呼吸系统防护 可能接触其粉尘时，应该佩戴过滤式防尘呼吸器 眼睛防护 戴化学安全防护眼镜 身体防护 穿隔绝式防毒服 手防护 戴橡胶手套 其他防护 工作现场严禁吸烟。工作完毕，淋浴更衣。注意个人清洁卫生。 (9)理化特性 外观与性状 白色或淡黄色细粒，微有苦杏仁气味 for more than 60 years of rural senior party member care funds; System of regulating the activities of grass-roots party organizations, and enhance the sense of belonging of grass-roots party members; Hold fast to implement "red credit", "red stake" two major project opportunities, strive to explore new ways of development of village collective economy, rural collective economy achieve breakthrough; A progress review by the Secretary of the party work of grass-roots party organizations, strengthens the responsibility of grasping party building, Party Secretary. Second, strengthening the construction of clean and honest Government and fight against corruption. Seriously implement the honest responsibility, actively carry out the independent Commission against corruption interview system, increase the leadership and the day-to-day supervision of party members and cadres at all levels, strengthen the not Winds of special treatment, treatment of "laid-back luxury and arrogance" and "three-pronged" problem, non-gang, national public officers, serving in leadership positions is not land, above-standard equipped with buses and cars for private purposes, and recreational city of gifts, hospitality, luxury and waste, "emptied the rating" special rectification work. Adhere to the rot will be punishing, corrupt Su, and 1 village, 4 disciplinary administrative cadres and workers. Three is to strengthen peace to create a work. Strengthen source management, adhere to prevention, focusing on prevention. Carry out the "big reception, big tour" campaign, petitioning for the cadres of the PH值 无意义 熔点(?)103,108 沸点(?)分解(爆炸) 相对密度(水=1)1.33 相对蒸气密度(空气=1)无资料 燃烧热(KJ/mol)-6855.2 临界压力(Mpa)2.57 辛醇/水分配系数 3.46 闪点(?)80 引燃温度(?)80 爆炸下限(%)无资料 爆炸上限(%)无资料 溶解性 不溶于水，微溶于醇类，溶于丙酮、苯、二硫化碳、氯仿等 主要用途 用作聚合反应催化剂，用于油脂的精制、蜡的脱色、医药的 制造等。 (10)稳定性和反应性 稳定性 不稳定 禁配物 强还原剂、酸类、碱、醇类 避免接触的条件 受热、光照、摩擦、震动 聚合危害 不聚合 分解产物 二氧化碳、苯甲酸、苯、苯甲酸苯酯 (11)毒理学资料 急性毒性 LD:7710mg/kg(大鼠经口) 50 刺激性 家兔经眼:500mg(24h),轻度刺激 (12)生态学资料 生态毒性 无资料 生物降解性 好氧生物降解(h):24,168 for more than 60 years of rural senior party member care funds; System of regulating the activities of grass-roots party organizations, and enhance the sense of belonging of grass-roots party members; Hold fast to implement "red credit", "red stake" two major project opportunities, strive to explore new ways of development of village collective economy, rural collective economy achieve breakthrough; A progress review by the Secretary of the party work of grass-roots party organizations, strengthens the responsibility of grasping party building, Party Secretary. Second, strengthening the construction of clean and honest Government and fight against corruption. Seriously implement the honest responsibility, actively carry out the independent Commission against corruption interview system, increase the leadership and the day-to-day supervision of party members and cadres at all levels, strengthen the not Winds of special treatment, treatment of "laid-back luxury and arrogance" and "three-pronged" problem, non-gang, national public officers, serving in leadership positions is not land, above-standard equipped with buses and cars for private purposes, and recreational city of gifts, hospitality, luxury and waste, "emptied the rating" special rectification work. Adhere to the rot will be punishing, corrupt Su, and 1 village, 4 disciplinary administrative cadres and workers. Three is to strengthen peace to create a work. Strengthen source management, adhere to prevention, focusing on prevention. Carry out the "big reception, big tour" campaign, petitioning for the cadres of the 厌氧生物降解(h):96,672 非生物降解性 光解最大光吸收波长范围(nm):235,275 空气中光氧化半衰期(h):51,510 生物富集性 BCF:250(理论) (13)废弃处置 废弃物性质 危险废物 废弃处置方法 用控制焚烧法处置。与不燃性物料混合后，再焚烧。 废弃注意事项 处置前应参阅国家和地方有关法规 (14)运输信息 危险货物编号 52045 铁危编号 52045 UN编号 3102;3104;3106;3107;3108;3109 包装类别 ?类包装 包装标志 有机过氧化物 包装方法 整车运输:装入螺纹口玻璃瓶，旋紧瓶盖，再装入坚固木箱，箱内用不燃材料填塞妥实，每箱净重不超过30kg，每瓶净重不超过5kg;塑料袋或二层牛皮纸袋外全开口或中开口钢桶(钢板厚0.5m，每桶净重不超过50kg);螺纹口玻璃瓶、塑料瓶或塑料袋外普通木箱。零担运输:塑料袋或二层牛皮纸袋外全开口或中开口钢桶(钢板厚0.5mm，每桶净重不超过50kg)，桶外加花格箱;螺纹口玻璃瓶、塑料瓶或塑料袋外普通木箱。 运输注意事项 铁路运输时应严格按照铁道部《危险货物运输规则》中的危险货物配装表进行配装。运输时单独装运，运输过程中要确保容器不泄露、不倒塌、不坠落、不损坏。运输时运输车辆应配备相应品种和数量的消for more than 60 years of rural senior party member care funds; System of regulating the activities of grass-roots party organizations, and enhance the sense of belonging of grass-roots party members; Hold fast to implement "red credit", "red stake" two major project opportunities, strive to explore new ways of development of village collective economy, rural collective economy achieve breakthrough; A progress review by the Secretary of the party work of grass-roots party organizations, strengthens the responsibility of grasping party building, Party Secretary. Second, strengthening the construction of clean and honest Government and fight against corruption. Seriously implement the honest responsibility, actively carry out the independent Commission against corruption interview system, increase the leadership and the day-to-day supervision of party members and cadres at all levels, strengthen the not Winds of special treatment, treatment of "laid-back luxury and arrogance" and "three-pronged" problem, non-gang, national public officers, serving in leadership positions is not land, above-standard equipped with buses and cars for private purposes, and recreational city of gifts, hospitality, luxury and waste, "emptied the rating" special rectification work. Adhere to the rot will be punishing, corrupt Su, and 1 village, 4 disciplinary administrative cadres and workers. Three is to strengthen peace to create a work. Strengthen source management, adhere to prevention, focusing on prevention. Carry out the "big reception, big tour" campaign, petitioning for the cadres of the 防器材及泄露应急处理设备。严禁与酸类、易燃物、有机物、还原剂看、自燃物品、遇湿易燃物品等并车混运。车速要加以控制，避免颠簸、震荡。夏季应早晚运输，防止日光曝晒。运输车辆装卸前后，均应彻底清扫、洗净，严禁混入有机物、易燃物等杂质。 (15)法规信息 中华人民共和国安全生产法(2002年6月29日第九届全国人大常委会第二十八次会议通过);中华人民共和国职业病防治法(2001年10月27日第九届全国人大常委会第二十四次会议通过);中华人民共和国环境保护法(1989年12月26日第七届全国人大常委会第十一次会议通过);危险化学品安全管理(2002年1月9日国务院第52次常务会议通过);安全生产许可证条例(2004年1月7日国务院第34次常务会议通过);常用危险化学品的分类及标志(GB13690-92);工作场所有害因素职业接触限值(GBZ2.1-2007)危险化学品名录。 for more than 60 years of rural senior party member care funds; System of regulating the activities of grass-roots party organizations, and enhance the sense of belonging of grass-roots party members; Hold fast to implement "red credit", "red stake" two major project opportunities, strive to explore new ways of development of village collective economy, rural collective economy achieve breakthrough; A progress review by the Secretary of the party work of grass-roots party organizations, strengthens the responsibility of grasping party building, Party Secretary. Second, strengthening the construction of clean and honest Government and fight against corruption. Seriously implement the honest responsibility, actively carry out the independent Commission against corruption interview system, increase the leadership and the day-to-day supervision of party members and cadres at all levels, strengthen the not Winds of special treatment, treatment of "laid-back luxury and arrogance" and "three-pronged" problem, non-gang, national public officers, serving in leadership positions is not land, above-standard equipped with buses and cars for private purposes, and recreational city of gifts, hospitality, luxury and waste, "emptied the rating" special rectification work. Adhere to the rot will be punishing, corrupt Su, and 1 village, 4 disciplinary administrative cadres and workers. Three is to strengthen peace to create a work. Strengthen source management, adhere to prevention, focusing on prevention. Carry out the "big reception, big tour" campaign, petitioning for the cadres of the