博禄PP上吹薄膜原料

吹膜级增强PPBorstar®技术2010年4月20日上海1April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©.Borouge博禄.Borstar®PP吹膜级聚丙烯.Borstar®PP工艺及优点.Borstar®PP牌号.Borpact™BC918CF.Borclear™RB707CF.实际应用2April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borouge博禄….资源,原料及技术的领导者3April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©我们的使命:革新,创造塑料解决的带头人4April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©以Borstar®技术为基础,以革新为导向确保价值链的可持续发展常规途径ReduceFeedstockOlefinsPolyolefinsRecycleRecover一体化价值链ReduceFeedstockOlefinsPolyolefinsConvertersEndusersConsumersRecycleRecover5April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borouge和Borealis–国际塑料市场的推动力BorougeHeadOfficeBorougeSalesandMarketingHeadOfficeBorougeproductionBorougesalesoffices/agentsBorougerepresentativeofficeInnovationCentreEuropeancustomerservicecentreBorealisHeadOfficeBorealisproduction6April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borouge石化….双峰聚乙烯Borstar®专利技术.年产量600,000吨成品.年产量600,000乙烯单体.中东地区HSE及生产荣誉认证7April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borouge2:三倍烯烃产量扩容.2,000,000吨/年成品.140万吨/年乙烯单体.75.2万吨/年丙烯单体.Borstar®增强聚乙烯54万吨/年.Borstar®聚丙烯80万吨/年.80%已完成>2010中开工.员工1,4008April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borouge3:巨资扩容.150万吨/年乙烯单体.Borstar®增强聚乙烯108万吨/年.Borstar®聚丙烯90万吨/年.35万吨/年LDPE:电线电缆.450万吨/年聚烯烃-2013年.聚烯烃FEED阶段9April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borouge2:物流网AbuDhabi-UAEShanghai-ChinaGuangzhou-ChinaSingapore-SEA10April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©目录.Borouge博禄.Borstar®PP吹膜级聚丙烯.Borstar®PP工艺及优点.Borstar®PP牌号.Borpact™BC918CF.Borclear™RB707CF.实际应用11April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borstar®PP上吹加工.传统上吹工艺.无规/嵌段共聚物融合耐热性,韧性并接近PE的透明度.Borclear™.Borpact™12April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borstar®PP吹膜牌号Borclear™RB707CFBorpact™BC918CFMFR1.53.0Flex.modulus8001450VicatSoftening125154SIT120140Haze<8<13Gloss>70>35无规嵌段.Borclear™高透明,可热封.Borpact™高冲击强度,挺度及透明度13April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©PP吹膜:为什么市场需求?.巨大的吹膜产能.更大竞争力.多样化/市场机遇PP两大卖点:.高挺度减薄.耐热延长消毒后的货架期市场趋势14April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©PP吹膜指南BUR2:1to3:1挤出温度:240C]°[..230度温220内冷+空气冷却210(温度推荐10-15°C)模口间隙1-2mm熔体2001900.3–0.50.8–1.82.0–3.0MFR230/2,16[g/10´]沟槽式进料,屏障型螺杆,L/D>28温度设置参数RB707CF/BC918CF:螺杆连接器模头190,200,210,220°C215,220°C225°C15April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borstar®PP常见问题指南问题原因解决方案熔体破裂熔体温度低1.2–1.5mm膜内微观结构差模口间隙宽或模头处氧化料堆积PPA(~1%)加工助剂清洗模头丝纹检查稳泡架的高度升高模头温度纵横向起皱纹夹辊及A字板温度低提高挤出量或降低模头与夹辊距离升高熔体温度减小冷却分层PE/PP共混常见加入>15%mLLDPE膜泡稳定性差冷却风太大调整风量或改变风环设计熔体温度太高降低熔体温度模口间隙宽建议1.2–1.5mm模口间隙膜间粘连熔体温度高降低熔体温度加入(slip+AB)光学性能差高霜冷线降低FLH原始料残留清洗挤出机30min使用骤冷气体16April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©目录.Borouge博禄.Borstar®PP吹膜级聚丙烯.Borstar®PP工艺及优点.Borstar®PP牌号.Borpact™BC918CF.Borclear™RB707CF.实际应用17April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borstar®多峰PP技术较好提升以下性能:提升.纯度.热封及光学性能.加工性.挺度.耐热性能并可.降低成本/无额外投资.替代CPP19April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©聚烯烃吹膜:光学-机械性能的平衡透明mLLDPEBorclear™Borpact™LDPE+LLDPEPP-光学性能HomoBorsoft™PP-HDPEBlockcopo亚光柔软挺度机械性能20April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©PP/PE–耐热性能LDPE(0.924)95°CPEHDPE(0.945)116°CRandom/Impact118°CPPImpact150°CRandom124°CHomo152°CHomonucl.157°C0306090120150180维卡软化点(°C)21April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©PP/PE–低温性能-40°CLDPE(0.924)PE-40°CHDPE(0.945)-25°CRandom/ImpactPP-20°CImpact-10°CRandomPP-Homo+5°CPP–Homonucl.+7°C-40-30-20-10010脆化温度(°C)22April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™vs.Borpact™热封性能3035BorclearRB707CFBorpactBC918CF25302520[N/15mm][N/15mm]201515strengthstrength1010SealSealSealstrengthstrengthSeal5500116118120122124126128136138140142144146148Sealingtemperature[°C]Sealingtemperature[°C]RB707CFBC918CF23April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™vs.Borpact™热粘性能2.02.5BorclearRB707CFBorpactBC918CF2.01.51.51.01.00.5Hot-tackstrength[N/15mm]strengthHot-tackHot-tackstrength[N/15mm]strengthHot-tack0.50.00.0100105110115120125130125130135140145150Sealingtemperature[°C]Sealingtemperature[°C]RB707CFBC918CF24April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©目录.Borouge博禄.Borstar®PP吹膜级聚丙烯.Borstar®PP工艺及优点.Borstar®PP牌号.Borpact™BC918CF.Borclear™RB707CF.实际应用25April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borpact™-BC918CF:多种性能的综合体挺度.复合立袋.食品包装.标签膜.托盘及盖材膜26April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borpact™:嵌段共聚物的新里程Sealstrength.透明,挺度,韧性于一体GlossSealtoughness.高热封强度.易撕.135°C蒸煮.低温韧性HazeFilm.加工的多样性stiffnessDDIF50EasytearBC918CFforBFapplicationsadvancedrandomcopolymer(RB707CF)standardImpactPP27April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©(BNT)成核技术––BC918CF：高挺度无成核剂PP(BNT)成核PP拉伸模量BNT=Borstar®反映釜中的成核决定了最终产品的感无成核剂1200MPa官,光学及机械性能含成核剂1450MPa28April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™RB707CF:无规共聚物Borclear:新一代无规共聚物Borclear™主要优点:.光学性能.热封窗口宽.耐热性.挺度.印刷性.低萃取物.产品间易切换29April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™/Borpact™vs.PEGloss[%]75684Haze[%]35SIT[°C]611814103140BorclearTMRB707CF80105BorpactTMBC918CF175124250180mLLDPE/LDDDIF50[g]155VicatA[°C]9001550Modulus23°C[MPa]30April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©目录.Borouge博禄.Borstar®PP吹膜级聚丙烯.Borstar®PP工艺及优点.Borstar®PP牌号.Borpact™BC918CF.Borclear™RB707CF.实际应用31April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©BC918CF/RB707CF:可剥离盖材膜结构:8µm–12µm剥离层(SteripeelWD170)1140µmPP阻隔层(BorpactTMBC918CF/1.2层共挤薄膜BorclearRB707CF)22粘结层基材(e.g.OPET,OPA,BOPP,Alu,…)332.复合4Borpact™/Borclear™特点.蒸煮.挺度.加工.低味.光学性能蒸煮/高挺度32April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™RB707CF：复合/食品–共挤薄膜结构:.40µm复合膜层间厚度分布:3/4/33层共挤外层:50%C4+24.5%LD+25%mLL+PPA中层:72%RB707CF+25%mLL+3%PPA/S/AB内层:74%mLL+20%LDS/AB+6%S/AB/PPA.15µmPE挤出涂覆复合.20µm基材,BOPPBorclear™特点:.减薄>25%(55to40µm).代替50/50LDPE和C4共混.提高挺性/加工.透明.低味减薄,提高挺性33April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borpact™BC918CF:共挤–蒸煮立袋ABorpact™BC918CF(40%RB707CF)BBorpact™BC918CFABorpact™BC918CF(40%RB707CF)(RB707提高热封及透明性)Borpact™:.韧性/挺度的平衡.封口强度.纯度/低味.垂直易撕.135°C蒸煮蒸煮/热封强度34April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™/Borpact™:面包袋ABorclear™RB707CF+mLLBBorpact™BC918CF+mLLABorclear™RB707CF+mLLBorclear™/Borpact™:.透明/挺性.减薄.热封.低味.消毒挺性/减薄35April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™RB707CF内衬袋Borclear™共混:.RB707CF+mLLDPE“易撕,快速打开内衬袋Borclear™:.高透明/更强吸引力.易撕.挺度.储藏高透明/易撕36April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™RB707CF-纸巾窗口Borclear™共混:.LLDPE+RB707CF(>30%RB707CF)Borclear™:.高透明度.提高挺度.减薄提高挺度/潜在减薄37April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™RB707CF:共挤FFS食品包装ABorstarPE+mLLBRB707CF+mLLABorstarPE+mLLBorclear™/Borpact™:.透明/挺度.减薄10-20%.宽热封窗口.无热封稀释/高产量.低温性减薄/宽热封窗口38April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borclear™RB707CF:收缩膜ARB707CFBLDPE+*mLLDARB707CFBorclear™:.高光学性能/挺度过.非粘连.减薄10-20%.可热封.可印刷/高产量.高收缩力*mLLD>15%非粘连/高收缩力39April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borpact™BC918CF:纸巾外包膜AmLLBBC918CFAmLLBorpact™:.挺度.垂直易撕扯.宽封口温度.高产量.减薄10-20%高模量40April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©Borpact™BC918CF:肉类包装薄膜结构:.7层:mLLD/Tie/PA/EVOH/PA/Tie/Borpact.5层:Borstar/Tie/EVOH/Tie/BorpactBorpact™:.代替PET.光学及挺度.无需复合/成本低.耐热.低温无需复合/挺度41April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©RB707CF(WD170CF):自排气微波炉食品袋薄膜结构:•65µm复合膜(1/2/1).3层共挤吹膜外层:C4+LDPE中层:50%RB707CF+35%mLL+C4+15%WhiteMB内层:WD170CF.复合•粘结层•12-15µm基材,PETalt.PA应用:自排气食品袋在加热食品时利用气体膨胀自行排气,简捷方便耐热,可热封及挺度42April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©RB707CF(WD170CF):自排气微波炉食品袋挑战:•耐热☺•自排气/平衡热封强度•穿刺性•低温性•挺性/加工性•光学性•低味道耐热,热封,提高挺度43April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©时间：2010年4月21日地点:上海海湾石化金山威尔路２３１号产品演示：FB2230,FB2310应用:重包装袋44April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©谢谢!问题…?45April23,2010©2006Borouge2006©Reference©2006BorealisAGAGBorealis2006©